Spin crossover-graphene nanocomposites: facile syntheses, characterization, and magnetic properties

被引:26
|
作者
Qiu, Dan [1 ]
Ren, Dong-Hong [1 ]
Gu, Ling [1 ]
Sun, Xiao-Li [1 ]
Qu, Ting-Ting [1 ]
Gu, Zhi-Guo [1 ,2 ]
Li, Zaijun [1 ]
机构
[1] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China
[2] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Food Colloids & Biotechnol, Wuxi 214122, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC FRAMEWORKS; THERMAL HYSTERESIS; NANOPARTICLES; SIZE; REDUCTION; SYNERGY; OXIDE;
D O I
10.1039/c4ra04257c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile way to fabricate spin crossover-graphene nanocomposites has been developed, and [Fe(Htrz)(2)(trz)](BF4)-graphene (SCO-G) nanocomposites have been successfully synthesized and characterized. SEM and TEM demonstrated that [Fe(Htrz)(2)(trz)](BF4) nanoparticles (ca. 50 nm) were distributed uniformly onto the surface of the graphene. Interestingly, graphene as a substrate produced an effect on the spin crossover properties of [Fe(Htrz)(2)(trz)](BF4) nanoparticles.
引用
收藏
页码:31323 / 31327
页数:5
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