Iodine induced transformations of alcohols under solvent-free conditions

被引：38
|
作者：
Stavber, Gaj.
Zupan, Marko
Stavber, Stojan
机构：
[1] Jozef Stefan Inst, Organ & Bioorgan Chem Lab, Ljubljana 1000, Slovenia
[2] Univ Ljubljana, Fac Chem & Chem Technol, Ljubljana 1000, Slovenia
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 48期
关键词：
iodine; solvent-free; alcohols; catalyst;
D O I：
10.1016/j.tetlet.2006.09.154
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Iodine has been shown to be an efficient catalyst for transformations of alcohols under solvent-free conditions. In the presence of 5% of iodine, tertiary alcohols underwent dehydration forming the corresponding alkenes, while in the case of 2-phenylpropane-2-ol cyclodimerisation to 1,1,3-trimethyl-3-phenylindane took place. Secondary and primary benzyl alcohols under the same conditions gave the corresponding ethers. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8463 / 8466
页数：4
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