Magnetic properties of a [Co(II)Cu(II)] bimetallic chain incorporating the obp = oxamidobis(N,N′-propionato) ligand

被引：0

作者：

Sra, AK ^{[1
]}

Kahn, O

Yakhmi, JV

机构：

[1] ICMCB, UPR 9048, Lab Sci Mol, F-33608 Pessac, France

[2] Bhabha Atom Res Ctr, Div Chem, Bombay 400085, Maharashtra, India

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1999年 / 335卷

关键词：

Co(II)Cu(II) bimetallic chains; long range magnetic order;

D O I：

暂无

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Dehydration of single crystals of the non-magnetic molecular compound CoCu(obp)(H2O)(3). H2O yields a compound CoCu(obp) which exhibits long range magnetic order. However, the magnetic transition temperature is rather low ( viz. 7 K) and its M(H) plot shows no hysterisis width, which is unusual for a compound derived from Co(II)Cu(II) bimetallic chains. The origin of this magnetic behaviour appears to lie in the absence of the first-order angular momentum of the parent compound CoCu(obp)(H2O)(3). H2O.

引用

页码：713 / 721

页数：9

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