Paleoproterozoic granulites from the Xinghe graphite mine, North China Craton: Geology, zircon U-Pb geochronology and implications for the timing of deformation, mineralization and metamorphism

The Xinghe graphite deposit is located in the north-central part of the North China Craton (NCC) where Archean gray gneiss, metasedimentary rocks (khondalites) and mafic (high-pressure) granulites constitute the dominant rock types. In this study, we report results of detailed geological and structural mapping around the Xinghe graphite mine. We identify three stages of deformation (D-1-D-3) and the graphite mineralization is correlated with D-1 or between D-1 and D-2. The first stage of deformation represented by rootless intrafolial folds whose axial surface cuts across the regional penetrative gneissosity (S-2) of D-2, was constrained at ca. 1.95-1.90 Ga by U-Pb age of zircon grains from a mafic high-pressure granulite. The second stage of deformation is represented by tight folds with formation of regional penetrative foliation and strong ductile shearing, when garnet broke down to plagioclase + pyroxene. This stage is dated as ca 1.85 Ga, from U-Pb analysis of zircons in leucosome from a migmatitic gneiss. The third stage of deformation is represented by large scale folding, which probably formed between 1.85 and 1.80 Ga, as constrained from the ca. 1.80 Ga emplacement age of an undeformed pegmatite that cuts across the host metasediments. Prior to the high-pressure granulite metamorphism, voluminous ca. 2.15-2.0 Ga granites were emplaced within the khondalites. The graphitization postdates the emplacement of these granites as deduced from the presence of flaky graphites in the metagranites. The protolith of the mafic high-pressure granulite dike that intruded the khondalite at ca. 2.0 Ga was also metamorphosed at 1.95-1.90 Ga, and is part of the exploited graphite ore body. We therefore constrain the timing of graphite mineralization to be between ca. 1.95 and 1.85 Ga. Our geological and geochronological data indicate that all the rock units in the Xinghe graphite mine were subjected to high-pressure granulite fades metamorphism at ca. 1.95-1.90 Ga. (C) 2014 Elsevier B.V. All rights reserved.