Deoxydehydration of Glycols Catalyzed by Carbon-Supported Perrhenate

被引：81
|
作者：
Denning, Alana L. [1 ]
Dang, Huong [2 ]
Liu, Zhimin [1 ]
Nicholas, Kenneth M. [2 ]
Jentoft, Friederike C. [1 ]
机构：
[1] Univ Oklahoma, Norman, OK 73019 USA
[2] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA
来源：
CHEMCATCHEM | 2013年 / 5卷 / 12期
基金：
美国国家科学基金会;
关键词：
alkenes; chemoselectivity; heterogeneous catalysis; regioselectivity; supported catalysts; BIOMASS; DEOXYGENATION; CONVERSION; POLYOLS; DIOLS; COMPLEXES; ROUTES; HYDROGENOLYSIS; TRANSFORMATION; HYDROGENATION;
D O I：
10.1002/cctc.201300545
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Support group: The first heterogeneous catalyst for the deoxydehydration (DODH) of glycols into olefins is reported. A carbon-supported perrhenate material was found to catalyze the reductive conversions of styrene diol, tetradecane diol, and diethyl tartrate into their respective olefins with high chemo-, regio-, and stereoselectivity. Effective reductants for this DODH reaction include H2, alcohols, and tetralin. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3567 / 3570
页数：4
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