Infrared and Raman spectra of bis-thiourea lead(II) chloride

被引：4
|
作者：
Faulques, E
Zubkowski, JD
Perry, DL
机构：
[1] JACKSON STATE UNIV,DEPT CHEM,JACKSON,MS 39217
[2] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,BERKELEY,CA 94720
来源：
SPECTROSCOPY LETTERS | 1996年 / 29卷 / 07期
关键词：
environmental materials; heavy metals; lead; vibrational spectra; bis-thiourea lead chloride; low temperature spectra;
D O I：
10.1080/00387019608007121
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
PbCl2.2[(SC(NH2)(2)] is an important complex for environmental chemistry. Single crystals were studied using infrared absorption, and Raman spectroscopy in low temperature conditions (10 K). Assignments of the lead complex bands were made by searching correlations and group Frequencies with separate PbCl2 and thiourea spectra in the solid state. Lattice modes separation was achieved down to 20 cm(-1) in Raman and down to 50 cm(-1) with far infrared spectroscopy. Spectral signatures of the unusual seven-coordinated lead in the complex were tentatively determined and are in accordance with structural data.
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收藏
页码：1275 / 1284
页数：10
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