Efficient facilitated transport of lead, cadmium, zinc, and silver across a flat-sheet-supported liquid membrane mediated by lasalocid A

被引:106
|
作者
Canet, L [1 ]
Ilpide, M [1 ]
Seta, P [1 ]
机构
[1] Lab Mat & Proc Membranaires, CNRS, UMR 5635, F-34293 Montpellier 05, France
关键词
D O I
10.1081/SS-120003047
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Flat-sheet-supported liquid membranes incorporating lasalocid A (a natural ionophore) were shown in previous works to achieve the transport of divalent transition metal cations such as Cd2+ and Zn2+ against a proton gradient, which is the driving force behind the process. This transport process has been extended to other metal species such as Pb2+ and Ag+ and also to the case where the two metal species compete for transport. A higher transport flux for Pb2+ as compared to Cd2+ and Zn2+ is observed, which is partly explained by a higher rate of interfacial complexation due to a smaller hydration shell of this species. This effect is confirmed by the data obtained with Ag(I).
引用
收藏
页码:1851 / 1860
页数:10
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