Acidity Characterization of Solid Acid Catalysts by Solid-State 31P NMR of Adsorbed Phosphorus-Containing Probe Molecules

被引：27

作者：

Zheng, Anmin ^{[1
]}

Deng, Feng ^{[1
]}

Liu, Shang-Bin ^{[2
,3
]}

机构：

[1] Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance,Key Lab Magnet Resonan, Wuhan 430071, Peoples R China

[2] Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan

[3] Natl Taiwan Normal Univ, Dept Chem, Taipei, Taiwan

来源：

ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 81 | 2014年 / 81卷

关键词：

Solid acid catalysts; Phosphorus-containing molecules; Solid-state NMR; Acidity; P-31 chemical shift; METHANE DEHYDRO-AROMATIZATION; GOLDBURG CROSS-POLARIZATION; NUCLEAR-MAGNETIC-RESONANCE; BRONSTED ACIDITY; CHEMICAL-SHIFT; H-MORDENITE; ZEOLITE HY; TRIMETHYLPHOSPHINE OXIDE; PHOSPHINE OXIDES; SURFACE-ACIDITY;

D O I：

10.1016/B978-0-12-800185-1.00002-4

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Recent developments on acidity characterization of solid acid catalysts, specifically those invoking P-31 solid-state nuclear magnetic resonance (SSNMR) spectroscopy using phosphorus-containing molecules as probes, have been summarized. In particular, various P-31 SSNMR approaches using trimethylphosphine, diphosphines, and trialkylphosphine oxides (R3PO) will be introduced, and their practical applications for the characterization of important qualitative and quantitative features, namely, type, distribution, accessibility (location/proximity), concentration (amount), and strength of acid sites in various solid acids, will be illustrated.

引用

页码：47 / 108

页数：62

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