Enantioselective ene reaction of cyclopentadiene and α,β-enals catalyzed by a diphenylprolinol silyl ether

被引：91

作者：

Gotoh, Hiroaki ^{[1
]}

Masui, Ryouhei ^{[1
]}

Ogino, Hiroshi ^{[1
]}

Shoji, Mitsuru ^{[1
]}

Hayashi, Yujiro ^{[1
]}

机构：

[1] Tokyo Univ Sci, Fac Engn, Dept Ind Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 41期

关键词：

asymmetric synthesis; cyclopentadiene; Diels-Alder reaction; ene reaction; organocatalysis;

D O I：

10.1002/anie.200602925

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The opposite result: A diphenylprolinol silyl ether promotes an intermolecular enantioselective ene reaction of α,β-enals with cyclopentadiene. This is the first example of cyclopentadiene acting as the ene component, and not the diene, with α,β-enals. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6853 / 6856

页数：4

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