Reactions and kinetics of unsaturated C2 hydrocarbon radicals

被引：106

作者：

Laufer, AH ^{[1
]}

Fahr, A ^{[1
]}

机构：

[1] Natl Inst Stand & Technol, Phys & Chem Properties Div, Gaithersburg, MD 20899 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 06期

关键词：

D O I：

10.1021/cr030039x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of the C2 unsaturated hydrocarbon radicals represent an important field of work that is relevant to macroscopic reaction media, such as combustion and environmental processes. The reaction kinetics and mechanisms of product formation of C2 unsaturated hydrocarbon radicals, namely, ethynyl (C2H), vinylidene (H2C=C), and vinyl (C2H3) radicals, are reviewed. The thermochemistry as well as the production and detection of these radical species are outlined. Results of relevant computational studies are discussed, and preferred rate coefficients for the radical reactions presented.

引用

页码：2813 / 2832

页数：20

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