Imaging and Spectroscopy of Multiwalled Carbon Nanotubes during Oxidation: Defects and Oxygen Bonding

被引:79
|
作者
Barinov, Alexei [1 ]
Gregoratti, Luca [1 ]
Dudin, Pavel [1 ]
La Rosa, Salvatore [1 ]
Kiskinova, Maya [1 ]
机构
[1] Sincrotrone Trieste, I-34012 Trieste, Italy
关键词
GRAPHITE; PHOTOEMISSION; FUNCTIONALIZATION; PURIFICATION; ARRAYS; LAYERS; STATE; GAS;
D O I
10.1002/adma.200803003
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The gasification process, which increases the number of broken C-C bonds and the abundance of particular oxygenated functional groups, is shown to destroy carbon nanotubes (CNTs). The expansion of the defect density and dimensions leads to nonlinear consumption of the CNTs with increasing O dose. Some nanotubes are consumed faster than others, most probably due to higher defect densities.
引用
收藏
页码:1916 / 1920
页数:5
相关论文
共 50 条
  • [21] On multiwalled carbon nanotubes oxidation: Thermogravimetric, spectral and macrokinetic studies
    Zabuga, Viktor Ya.
    Bochechka, Oleksandr O.
    Tsapyuk, Galyna G.
    Diyuk, Vitaliy E.
    Panova, Anna M.
    Lisnyak, Vladyslav V.
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2018, 661 (01) : 81 - 90
  • [22] Catalytic systems of cumene oxidation based on multiwalled carbon nanotubes
    N. S. Kobotaeva
    T. S. Skorokhodova
    N. V. Ryabova
    Russian Journal of Physical Chemistry A, 2015, 89 : 462 - 468
  • [23] Influences of oxidation and reduction treatments on the properties of multiwalled carbon nanotubes
    Guo, Lifu
    Zou, Liming
    Wei, Yizhe
    Ling, Xinlong
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [24] Catalytic activity of multiwalled carbon nanotubes for the oxidation of nitric oxide
    Zhao, GC
    Wu, FH
    Wei, XW
    CHEMISTRY LETTERS, 2002, (05) : 520 - 521
  • [25] Effects of oxidation by hydrogen peroxide on the structures of multiwalled carbon nanotubes
    Peng, Yun
    Liu, Hewen
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (19) : 6483 - 6488
  • [26] Defect Structure of Multiwalled Carbon Nanotubes Studied by Raman Spectroscopy
    Baitinger, E. M.
    Vekesser, N. A.
    Kovalev, I. N.
    Ryabkov, Yu. I.
    Viktorov, V. V.
    INORGANIC MATERIALS, 2011, 47 (05) : 471 - 474
  • [27] Defect structure of multiwalled carbon nanotubes studied by Raman spectroscopy
    E. M. Baitinger
    N. A. Vekesser
    I. N. Kovalev
    Yu. I. Ryabkov
    V. V. Viktorov
    Inorganic Materials, 2011, 47 : 471 - 474
  • [28] Surface modification of multiwalled carbon nanotubes with oxygen and chlorine atoms
    Oliveira, Luciana
    Debies, Thomas
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [29] Raman study of multiwalled carbon nanotubes functionalized with oxygen groups
    Murphy, H
    Papakonstantinou, P
    Okpalugo, TIT
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2006, 24 (02): : 715 - 720
  • [30] Ion ranges and irradiation-induced defects in multiwalled carbon nanotubes
    Pomoell, JAV
    Krasheninnikov, AV
    Nordlund, K
    Keinonen, J
    JOURNAL OF APPLIED PHYSICS, 2004, 96 (05) : 2864 - 2871