Estimation of the critical rate of temperature rise for thermal explosion of autocatalytic decomposing reaction of nitrocellulose using non-isothermal DSC

被引：24
|
作者：
Ning, BK
Hu, RZ [1 ]
Zhang, H
Xia, ZM
Guo, PJ
Liu, R
Lu, GI
Jiang, JY
机构：
[1] Xian Modern Chem Res Inst, Xian 710065, Peoples R China
[2] NW Univ Xian, Dept Chem, Shaanxi Key Lab Physicoinorgan Chem, Xian 710069, Peoples R China
[3] NW Univ Xian, Dept Math, Xian 710069, Peoples R China
[4] Ordnance Engn Inst, Shijiazhuang 05000, Peoples R China
来源：
THERMOCHIMICA ACTA | 2004年 / 416卷 / 1-2期
关键词：
critical rate of temperature rise; DSC; increasing rate of temperatures NC; non-isothermal; thermal explosion;
D O I：
10.1016/j.tca.2003.11.029
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A method of estimating the critical rate of temperature rise for thermal explosion of empiric-order autocatalytic decomposition reaction system using non-isothermal DSC is presented. Information is obtained on the increasing rate of temperature in nitrocellulose containing 12.97% of nitrogen when the first-order autocatalytic decomposition converts into thermal explosion. (C) 2003 Elsevier B.V. All rights reserved.
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页码：47 / 50
页数：4
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