First stereoselective synthesis of enantiomerically pure telluronium salts by the reaction of chiral halooxatelluranes with Grignard reagents

被引：16

作者：

Zhang, J ^{[1
]}

Saito, S ^{[1
]}

Koizumi, T ^{[1
]}

机构：

[1] TOYAMA MED & PHARMACEUT UNIV,FAC PHARMACEUT SCI,TOYAMA 93001,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 20期

关键词：

D O I：

10.1016/S0957-4166(97)00459-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We prepared a series of enantiomerically pure benzyl and allyl telluronium salts 2 and 4, using the 2-exo-hydroxy-10-bornyl group as a chiral ligand, in high yield and selectivity by the reaction of chiral haloalkoxytelluranes 1 and 3 with Grignard reagents. A sharp pyramidal structure with S absolute configuration at the tellurium atom was confirmed by an X-ray analysis of 2c. (C) 1997 Published by Elsevier Science Ltd.

引用

页码：3357 / 3361

页数：5

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