Highly Efficient Organic Light-Emitting Diodes with Phosphorescent Emitters Having High Quantum Yield and Horizontal Orientation of Transition Dipole Moments

被引:318
|
作者
Kim, Kwon-Hyeon [1 ,2 ]
Moon, Chang-Ki [3 ,4 ]
Lee, Jeong-Hwan [1 ,2 ]
Kim, Sei-Yong [3 ,4 ]
Kim, Jang-Joo [1 ,2 ,3 ,4 ]
机构
[1] Seoul Natl Univ, WCU Hybrid Mat Program, Dept Mat Sci & Engn, Seoul 151744, South Korea
[2] Seoul Natl Univ, Ctr Organ Light Emitting Diode, Seoul 151744, South Korea
[3] Seoul Natl Univ, Dept Mat Sci & Engn, Seoul 151742, South Korea
[4] Seoul Natl Univ, Ctr OLED, Seoul 151742, South Korea
关键词
EMISSION;
D O I
10.1002/adma.201305733
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ancillary ligands in heteroleptic iridium complexes significantly influence the orientation of the transition dipole moments. Ir(ppy)(3), a homoleptic iridium complex, exhibits isotropic dipole orientation, whereas the heteroleptic Ir complexes of Ir(ppy)(2)tmd show a highly preferred dipole orientation (78%) in the horizontal direction. In addition, we demonstrate an unprecedented highly efficient green OLED exhibiting an EQE of 32.3% and a power efficiency of 142.5 lm/W by using an emitter with high quantum yield and horizontally oriented dipoles.
引用
收藏
页码:3844 / 3847
页数:4
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