Electrochemically induced transformation of 4-halomethyl-4-methylcyclohexa-2,5-dien-1-ones into 3,4-dimethylphenol

被引：3

作者：

Gavrilova, G. V. ^{[1
]}

Moiseeva, A. A. ^{[1
]}

Beloglazkina, E. K. ^{[1
]}

Gavrilov, A. A. ^{[1
]}

Zyk, N. V. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119992, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2009年 / 79卷 / 02期

关键词：

Glassy Carbon Electrode; Electrochemical Reduction; Cyclic Voltammetry Curve; Halogen Atom; Diethyl Malonate;

D O I：

10.1134/S1070363209020169

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical behavior of 4-halomethyl-4-methylcyclohexa-2,5-dien-1-ones and 2,6-dibromo-4,4-dimethylcyclohexa-2,5-dien-1-one was studied. Reductive dehalogenation of cyclohexa-2,5-dien-1-ones having a halogen atom at the neopentyl-like carbon atom gives the corresponding carbanion which undergoes anionic cyclopropyl-allyl rearrangement with subsequent addition of proton to form 3,4-dimethylphenol.

引用

页码：264 / 268

页数：5

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