Synthesis, characterization and luminescent properties of palladium complexes with 3-(2-pyridyl)-1H-1,2,4-triazole-5-acetic acid ethyl ester

被引：5
|
作者：
Khomenko, Dmytro M. [1 ]
Doroschuk, Roman O. [1 ]
Lampeka, Rostyslav D. [1 ]
机构：
[1] Kyiv Natl Taras Shevchenko Univ, Dept Chem, Kiev, Ukraine
来源：
POLYHEDRON | 2015年 / 100卷
关键词：
1,2,4-Triazole; Tetranuclear; Palladium; Luminescence; Complex; LIGANDS; TRIAZOLES;
D O I：
10.1016/j.poly.2015.06.036
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis, spectral characterization and luminescent properties of palladium(II) complexes with 3-(2-pyridyl)-1H-1,2,4-triazole-5-acetic acid ethyl ester (HL) have been described. The compounds Pd(L)(2) and Pd-4(L)(4)Cl-4 center dot 2DMF were prepared by refluxing Pd(HL)Cl-2 in DMF. The pathways of their formation were investigated using H-1 NMR spectroscopy. The molecular and crystal structures of Pd-4(L)(4)Cl-4 center dot 2DMF were determined by means of single crystal X-ray diffraction analysis. The triazoles in Pd-4(L)(4)Cl-4 center dot 2DMF were found to act as bidentate ligands bridging two palladium centers in two different Ways, so the molecular structure consists of tetranuclear units of palladium ions. The luminescence properties of the ligand and its complexes were discussed. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：82 / 88
页数：7
相关论文
共 50 条
  • [41] 1-(3-Bromopropyl)-4-(2-pyridyl)-1H-1,2,3-triazole
    Crowley, James D.
    Bandeen, Pauline H.
    Hanton, Lyall R.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O999 - U1828
  • [42] 3,4-Bis(2-pyridyl)-5-(3-pyridyl)-4H-1,2,4-triazole
    Wu, Jing-Min
    Guo, Wei
    Li, Cheng-Peng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1189 - U1006
  • [43] Silver(I) complexes of 1H-1,2,4-triazole-3-thiol, 3-amino-5-mercapto-1,2,4-triazole and 3-amino-5-methylthio-1,2,4-triazole
    Gabryszewski, M
    POLISH JOURNAL OF CHEMISTRY, 1996, 70 (09) : 1220 - 1222
  • [44] 3-(4-Nitrophenyl)-1H-1,2,4-triazole-5(4H)-thione
    Fun, Hoong-Kun
    Quah, Ching Kheng
    Nithinchandra
    Kalluraya, Balakrishna
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2413 - U989
  • [45] Bis[μ-3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole]bis[dichloridocopper(II)]
    Wang, Zuoxiang
    Liu, Chunyi
    Zhang, Xiaoming
    Gong, Xiaoning
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M22 - U320
  • [46] Palladium(II) complexes with 1-allyl-3-(2-pyridyl)thiourea: Synthesis and spectroscopic characterization
    Orysyk, S. I.
    Rybachuk, L. N.
    Pekhnyo, V. I.
    Orysyk, V. V.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2011, 56 (11) : 1747 - 1751
  • [47] Palladium(II) complexes with 1-allyl-3-(2-pyridyl)thiourea: Synthesis and spectroscopic characterization
    S. I. Orysyk
    L. N. Rybachuk
    V. I. Pekhnyo
    V. V. Orysyk
    Russian Journal of Inorganic Chemistry, 2011, 56 : 1747 - 1751
  • [48] 3-[(2-Hydroxybenzylidene) hydrazinocarbonyl]-1H-1,2,4-triazole ethanol solvate
    Ge, CH
    Yang, JG
    Pan, FY
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O833 - O835
  • [49] 5-Acylmethyl-3-(2-pyridyl)-1,2,4-triazines: Synthesis and Complexes with Cu(II)
    A. M. Prokhorov
    D. N. Kozhevnikov
    V. L. Rusinov
    A. I. Matern
    M. M. Nikitin
    O. N. Chupakhin
    I. L. Eremenko
    G. G. Aleksandrov
    Russian Journal of Organic Chemistry, 2005, 41 : 1702 - 1705
  • [50] Synthesis and characterisation of two high spin iron(II) complexes of 3,4-diphenyl-5-(2-pyridyl)-1,2,4-triazole
    Miller, Reece G.
    Jameson, Guy N. L.
    Olguin, Juan
    Brooker, Sally
    SUPRAMOLECULAR CHEMISTRY, 2012, 24 (08) : 547 - 552
12345