A free radical process for oxidation of hydrocarbons promoted by nonmetal xanthone and tetramethylammonium chloride under mild conditions

被引：30

作者：

Du, Zhongtian ^{[1
,2
]}

Sun, Zhiqiang ^{[1
]}

Zhang, Wei ^{[1
]}

Miao, Hong ^{[1
]}

Ma, Hong ^{[1
]}

Xu, Jie ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 15期

关键词：

Aerobic oxidation; Hydrocarbons; Xanthone; Nitroxyl radical; Quaternary ammonium salts; N-HYDROXYPHTHALIMIDE NHPI; QUATERNARY AMMONIUM-SALTS; MOLECULAR-OXYGEN; AEROBIC OXIDATION; METAL-FREE; HYDROGEN ABSTRACTION; CATALYTIC-OXIDATION; ELECTRON-TRANSFER; HIGHLY EFFICIENT; ONIUM SALTS;

D O I：

10.1016/j.tetlet.2009.01.077

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A nonmetal catalytic system consisting of N-hydroxyphthalimide, xanthone, and tetramethylammonium chloride was developed. A wide range of hydrocarbons could be oxidized efficiently with dioxygen under mild conditions. In the presence of xanthone and tetramethylammonium chloride, catalytic activity of N-hydroxyphthalimide was greatly improved, and selectivity for alkyl hydroperoxide was remarkably decreased. (C) 2009 Published by Elsevier Ltd.

引用

页码：1677 / 1680

页数：4

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