Aminocyclopentadienyl ruthenium chloride: Catalytic racemization and dynamic kinetic resolution of alcohols at ambient temperature

被引：1
|
作者：
Choi, JH [1 ]
Kim, YH [1 ]
Nam, SH [1 ]
Shin, ST [1 ]
Kim, MJ [1 ]
Park, J [1 ]
机构：
[1] Pohang Univ Sci & Technol, POSTECH, Div Mol & Life Sci, Dept Chem,Natl Res Lab Chirotechnol, Pohang 790784, South Korea
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 13期
关键词：
D O I：
10.1002/1521-3773(20020703)41:13<2373::AID-ANIE2373>3.0.CO;2-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ruthenium-enzyme tandem catalysis: The novel racemization catalyst 1 improves the dynamic kinetic resolution (DKR) of secondary alcohols dramatically. The DKR proceeds at room temperature with isopropenyl acetate as an acyl donor. In addition, the DKR is faster even with much less lipase than in previous DKRs.
引用
收藏
页码：2373 / 2376
页数：4
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