The structure and properties of β-La3RuO7:: A new structure type with isolated RuO6 octahedra

被引：10
|
作者：
Khalifah, P
Ho, DM
Huang, Q
Cava, RJ
机构：
[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
[2] Princeton Univ, Princeton Mat Inst, Princeton, NJ 08540 USA
[3] Natl Inst Stand & Technol, Ctr Neutron Res, Gaithersburg, MD 20899 USA
[4] Univ Maryland, Dept Mat & Nucl Engn, College Pk, MD 20742 USA
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2002年 / 165卷 / 02期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1006/jssc.2002.9551
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
second lanthanum ruthenium oxide with the formula La3RuO7 is reported. This compound, beta-La3RuO7, crystallizes in the P2(1)/c space group with a unit cell of a=8.8388(3)A, b = 5.6960(1) Angstrom, c = 12.5830(3) Angstrom, and beta = 104.729(1)degrees, as refined from powder neutron diffraction data. The two major structural motifs in this structure are isolated RuO6 octahedra and edge-sharing chains of OLa4 tetrahedra. Magnetic susceptibility measurements show this compound to have a magnetic moment of mu(eff) = 3.92 mu(B) and a Weiss constant of theta = -70 K. (C) 2002 Elsevier Science (USA).
引用
收藏
页码：359 / 362
页数：4
相关论文
共 50 条
  • [21] Structure, Magnetism, and First-Principles Modeling of the Na0.5La0.5RuO3 Perovskite
    Nguyen, Loi T.
    Saubanere, Matthieu
    Zhang, Qiang
    Cava, Robert J.
    CHEMISTRY OF MATERIALS, 2021, 33 (02) : 600 - 607
  • [22] MAGNETIC-PROPERTIES OF NEW CUBIC-PEROVSKITE MIXTURES - (LA0.5NA0.5)RUO3 AND (CA1-XAX)RUO3 (A=MG,SR)
    KANBAYASI, A
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1978, 44 (01) : 108 - 113
  • [23] SYNTHESIS AND STRUCTURE OF LI3RHH6 - A TERNARY HYDRIDE WITH ISOLATED [RHH6](3-) OCTAHEDRA
    BRONGER, W
    GEHLEN, M
    AUFFERMANN, G
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (11): : 1983 - 1985
  • [24] PROPERTIES OF NEW REM STANNIDES OF THE LA3CO2SN7 STRUCTURE
    SKOLOZDRA, RV
    YASNITSKAYA, IV
    AKSELRUD, LG
    UKRAINSKII FIZICHESKII ZHURNAL, 1987, 32 (05): : 729 - 732
  • [25] On NaBa3RuO6 and NaBa3IrO6. Two noble metal oxometallates showing Sr4PtO6 structure
    Frenzen, S
    MullerBuschbaum, H
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (08): : 1204 - 1206
  • [26] The structures and characterization of two new oxides of the Sr4PtO6 type: NaCa3IrO6 and NaCa3RuO6
    Claridge, JB
    Layland, RC
    Adams, RD
    zurLoye, HC
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (07): : 1131 - 1134
  • [27] Structure, morphology and composition of superconducting Sr2RuO4-Sr3Ru2O7 eutectic crystals
    Fittipaldi, R.
    Fusanobori, S.
    Kittaka, S.
    Yaguchi, H.
    Hooper, J.
    Vecchione, A.
    Maeno, Y.
    PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 2007, 460 : 524 - 525
  • [28] New rock salt-related oxides Li3M2RuO6 (M=Co, Ni): Synthesis, structure, magnetism and electrochemistry
    Laha, S.
    Moran, E.
    Saez-Puche, R.
    Alario-Franco, M. A.
    Dos Santos-Garcia, A. J.
    Gonzalo, E.
    Kuhn, A.
    Garcia-Alvarado, F.
    Sivakumar, T.
    Tamilarasan, S.
    Natarajan, S.
    Gopalakrishnan, J.
    JOURNAL OF SOLID STATE CHEMISTRY, 2013, 203 : 160 - 165
  • [29] Structural, magnetic and magnetocaloric properties in the rare earth ruthenate RE3RuO7 (RE = Pr, Nd, Gd and Tb) oxides with fluorite related structure
    He, Ningzhou
    Wang, Pengyu
    Huang, Jiaohong
    Wang, Xinhua
    Zhang, Yikun
    Hu, Liang
    Li, Lingwei
    Yan, Mi
    CERAMICS INTERNATIONAL, 2022, 48 (24) : 36968 - 36974
  • [30] Crystal structure, oxidation state and magnetism of La1.2Sr2.4RuO7:: a new member of the [A2O][AnBn-1O3n ] series of hexagonal perovskites
    Ebbinghaus, SG
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (03) : 817 - 823
12345