Self-Complementary Phosphonate Cavitands

被引：22

作者：

Dubessy, Beatrice ^{[1
]}

Harthong, Steven ^{[1
]}

Aronica, Christophe ^{[1
]}

Bouchu, Denis ^{[2
]}

Busi, Marco ^{[3
,4
]}

Dalcanale, Enrico ^{[3
,4
]}

Dutasta, Jean-Pierre ^{[1
]}

机构：

[1] Ecole Normale Super Lyon, CNRS, Chim Lab, F-69364 Lyon 07, France

[2] Univ Lyon 1, Ctr Spectrometrie Masse, F-69622 Villeurbanne, France

[3] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy

[4] Univ Parma, INSTM UdR Parma, I-43100 Parma, Italy

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 74卷 / 10期

关键词：

SUPRAMOLECULAR POLYMERS; COORDINATION CAGES; SPECTROSCOPY; DIFFUSION; COMPLEXES; CHEMISTRY; DESIGN;

D O I：

10.1021/jo900236n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

iii-Phosphorylated cavitands incorporating an N-methylpyridinium guest moiety as the fourth bridging unit form supramolecular associations by inclusion of the charged CH3N(+)-pyridinium head into a neighboring host cavity. The dimeric association is favored in solution and was characterized by NMR, mass spectrometry, DOSY experiments, and single crystal X-ray analysis.

引用

页码：3923 / 3926

页数：4

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