Introducing Dimensionality to the Archetypical Mn12 Single-Molecule Magnet: a Family of [Mn12]n Chains

被引：17
|
作者：
Corrales, Sergio A. [1 ]
Cain, John M. [1 ]
Uhlig, Kelley A. [1 ]
Mowson, Andrew M. [2 ]
Papatriantafyllopoulou, Constantina [3 ]
Peprah, Marcus K. [4 ,5 ]
Ozarowski, Andrew [6 ]
Tasiopoulos, Anastasios J. [3 ]
Christou, George [2 ]
Meisel, Mark W. [4 ,5 ]
Lampropoulos, Christos [1 ]
机构：
[1] Univ N Florida, Dept Chem, 1 UNF Dr, Jacksonville, FL 32224 USA
[2] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[3] Univ Cyprus, Dept Chem, CY-1678 Nicosia, Cyprus
[4] Univ Florida, Dept Phys, Gainesville, FL 32611 USA
[5] Univ Florida, NHMFL, Gainesville, FL 32611 USA
[6] Florida State Univ, NHMFL, Tallahassee, FL 32310 USA
来源：
INORGANIC CHEMISTRY | 2016年 / 55卷 / 04期
基金：
美国国家科学基金会;
关键词：
PRESSURE; DIMER;
D O I：
10.1021/acs.inorgchem.6b00058
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The [Mn12O12(O2CR)(16)(L-4)] family (R = various; L = terminal ligand) of clusters holds a special place in molecular magnetism; they are the most well studied single-molecule magnets (SMMs). Targeted linkage of these SMMs has now been achieved for the first time. The resulting chain structures have been confirmed crystallographically, and the magnetic properties, up to 1.14 GPa, and high-field electron paramagnetic resonance spectra have been collected and analyzed.
引用
收藏
页码：1367 / 1369
页数：3
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