Highly diastereoselective synthesis of a novel functionalized triepoxytrinaphthylene

被引：0

作者：

Erdogan, Musa ^{[1
]}

Essiz, Selcuk ^{[1
]}

Fabris, Fabrizio ^{[2
]}

Dastan, Arif ^{[1
]}

机构：

[1] Ataturk Univ, Fac Sci, Dept Chem, Erzurum, Turkey

[2] Univ Ca Foscari Venezia, Dipartimento Sci Mol & Nanosistemi, Venice, Italy

来源：

ARKIVOC | 2018年

关键词：

Cyclotrimerization; copper; cup-shaped molecules; stereoselective reactions; aromatic compounds; POLYMERIZATION PROCESSES; CYCLOTRIMERIZATION; (+)-SYN-BENZOTRIBORNEOL; OXABENZONORBORNADIENE; BENZOCYCLOTRIMER; ISOBENZOFURAN; ENCAPSULATION; COORDINATION; CONDENSATION; INFORMATION;

D O I：

10.24820/ark.5550190.p010.408

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The high yielding synthesis of a novel benzocyclotrimer is herein presented. The syn-diastereomer is obtained as major product, presumably in virtue of the presence of an oxa-bridge of the bicylic components. The three oxa-bridges can be used for further functionalization, as well as the six bromine atoms of the three aromatic rings, as demonstrated in the aromatization of a mixture of anti-1 and syn-1 (3:7) leading to trinaphthylene. [GRAPHICS] .

引用

页码：134 / 143

页数：10

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