Catalytic enantioselective synthesis of adociacetylene B

被引：63
|
作者：
Trost, Barry M. [1 ]
Weiss, Andrew H. [1 ]
机构：
[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
来源：
ORGANIC LETTERS | 2006年 / 8卷 / 20期
关键词：
D O I：
10.1021/ol0615836
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A catalytic enantioselective total synthesis of adociacetylene B (2) in five steps is reported. The efficiency of this synthesis was enabled by an asymmetric zinc alkynylation catalyzed by the proline-derived ligand (1).
引用
收藏
页码：4461 / 4464
页数：4
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