Liquid-vapor transition and critical behavior of the ultrasoft restricted primitive model of polyelectrolytes: A Monte Carlo study

被引:6
|
作者
Caillol, J. -M. [1 ]
Levesque, D.
机构
[1] Phys Theor Lab, UMR 8627, F-91405 Orsay, France
来源
JOURNAL OF CHEMICAL PHYSICS | 2014年 / 140卷 / 21期
关键词
IONIC FLUIDS; PHASE-TRANSITIONS; CRITICAL-POINT; UNIVERSALITY; SYSTEMS;
D O I
10.1063/1.4880239
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present a Monte Carlo study of the liquid-vapor transition and the critical behavior of a model of polyelectrolytes with soft Gaussian charge distributions introduced recently by Coslovich, Hansen, and Kahl [J. Chem. Phys. 134, 244514 (2011)]. A finite size study involving four different volumes in the grand canonical ensemble yields a precise determination of the critical temperature, chemical potential, and density of the model. Attempts to determine the nature of the criticality and to obtain reliable values for the critical exponents are not conclusive. (C) 2014 AIP Publishing LLC.
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页数:5
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