NaHSO3-Mediated Direct Synthesis of Sulfinic Esters from Sulfonyl Hydrazides under Transition-Metal-Free Conditions

被引：13
|
作者：
Zhang, Guofu [1 ]
Fan, Qiankun [1 ]
Wang, Huimin [1 ]
Zhao, Yiyong [2 ]
Ding, Chengrong [1 ]
机构：
[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China
[2] Zhejiang Ecol Environm Low Carbon Dev Ctr, Hangzhou 310012, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2021年 / 363卷 / 03期
基金：
中国国家自然科学基金;
关键词：
sulfonyl hydrazides; alcohols; sulfinic esters; transition-metal-free; radical pathway; ONE-POT SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; ARENESULFONYL CHLORIDES; EFFICIENT; ALKENES;
D O I：
10.1002/adsc.202001202
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
We have developed a protocol for the NaHSO3-promoted esterification of sulfonyl hydrazides with alcohols for the synthesis of sulfinic esters. Various sulfonyl hydrazides could be converted to the corresponding sulfinic esters in good to high yields. The merits of this protocol include mild transition-metal-free reaction conditions, an inexpensive and available reagent, and operational simplicity. Controlled experiments reveal that this transformation probably undergoes via a radical pathway.
引用
收藏
页码：833 / 837
页数：5
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