ONE-POT PREPARATION OF 2-ARYLBENZOFURANS FROM OXIMES WITH DIARYLIODONIUM TRIFLATE

被引：13

作者：

Miyagi, Kotaro ^{[1
]}

Moriyama, Katsuhiko ^{[1
]}

Togo, Hideo ^{[1
]}

机构：

[1] Chiba Univ, Grad Sch Sci, Inage Ku, Chiba 2638522, Japan

来源：

HETEROCYCLES | 2014年 / 89卷 / 09期

关键词：

METAL-FREE SYNTHESIS; 2,3-DISUBSTITUTED BENZOFURANS; FUNCTIONALIZED BENZOFURANS; SUBSTITUTED BENZOFURANS; EFFICIENT SYNTHESIS; SELECTIVE SYNTHESIS; CARBOXYLIC-ACIDS; O-ARYLATION; INDOLES; ETHERS;

D O I：

10.3987/COM-14-13071

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of 2-arylbenzofurans were obtained in good yields by the O-arylation of oximes with diaryliodonium triflates, followed by the treatment with HCl in dioxane under warming conditions through the [3,3]-sigmatropic reaction. The present reaction is one-pot transition metal-free method for the preparation of various 2-arylbenzofurans from oximes, which are easily available from the reaction of alkyl aryl ketones with hydroxylamine

引用

页码：2122 / 2136

页数：15

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