Novel NiTiO3/Ag3VO4 composite with enhanced photocatalytic performance under visible light

被引:83
|
作者
Inceesungvorn, Burapat [1 ]
Teeranunpong, Thidarin [1 ]
Nunkaew, J. [2 ]
Suntalelat, Sarunya [3 ]
Tantraviwat, Doldet [3 ]
机构
[1] Chiang Mai Univ, Fac Sci, Dept Chem, Chiang Mai 50200, Thailand
[2] Chiang Mai Univ, Fac Sci, Dept Phys & Mat Sci, Chiang Mai 50200, Thailand
[3] Natl Elect & Comp Technol Ctr NECTEC, Thai Microelect Ctr TMEC, Chachoengsao 24000, Thailand
关键词
Heterojunction; Composite; Nickel titanate; Silver vanadate; Visible light; HYDROTHERMAL SYNTHESIS; HETEROJUNCTION; REDUCTION;
D O I
10.1016/j.catcom.2014.05.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel NiTiO3/Ag3VO4 composite with type-II band alignment was prepared using a modified Pechini/precipitation method. The FESEM image of the NiTiO3/Ag3VO4 heterostructure reveals the dispersion of small NiTiO3 particles on the Ag3VO4 surfaces, indicating the close interfacial connection between NiTiO3 and Ag3VO4. The heterojunction shows remarkably higher photocatalytic activity than pure NiTiO3 and Ag3VO4 due to an increase in light harvesting efficiency and an efficient electron-hole separation being induced by the suitably matching conduction and valence band levels. Based on the VB-XPS and UV-vis DRS results, a possible electron-hole transfer mechanism at the NiTiO3/Ag3VO4 interface is proposed. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:35 / 38
页数:4
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