(2,2′-Dipyridyl sulfide-N,N′)hydroxy-bis(nitrito-O)(nitrogen monoxide-N)-ruthenium(III)

被引：0
|
作者：
Bruno, G [1 ]
Nicoló, F [1 ]
Tresoldi, G [1 ]
机构：
[1] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2000年 / 56卷
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Ru(NO2)(2)(OH)(C10H8N2S)(NO)]. is the main product of the reaction between RuCl3? and dps (dps is 2,2'-dipyridyl sulfide, C10H8N2S) in ethanol-water at room temperature followed by reaction with NaNO2 at a higher temperature. The Ru atom has a distorted octahedral coordination geometry with the dps molecule behaving as an N,N'-bidentate ligand, The six-membered chelate ring adopts a boat conformation.
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页码：282 / 283
页数：2
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