TBHP-mediated C-H thiolation of tetrahydrofuran with disulfides promoted by catalytic amounts of Na2CO3

被引：1

作者：

Tao, Li-Ming ^{[1
]}

Liu, Wen-Qi ^{[1
]}

Li, Chuan-Hua ^{[1
]}

Liu, Hui ^{[1
]}

机构：

[1] Xiangnan Univ, Dept Chem & Life Sci, Hunan Prov Key Lab Xiangnan Rare Precious Met Cpd, Chenzhou 423000, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2014年 / 05期

关键词：

tert-butyl hydroperoxide; oxidative cross coupling; 1,2-disulfides; tetrahydrofuran; base; sodium carbonate; ANTI-MARKOVNIKOV ADDITION; BOND FUNCTIONALIZATION; STRATEGY; ALKENES; THIOLS;

D O I：

10.3184/174751914X13961795538392

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient route to constructing C-S bonds has been developed by TBHP (tert-butyl hydroperoxide) mediated C-H thiolation of tetrahydrofuran with disulfides. This route is promoted by catalytic amounts of Na2CO3 and gives various tetrahydrofurancontaining sulfides in moderate to high yields.

引用

页码：280 / 282

页数：3

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