3-[(E)-2-(5,7-Dichloro-8-hydroxyquinolin-2-yl)vinyl]-4-hydroxyphenyl acetate

被引:7
|
作者
Ponikiewski, Lukasz [1 ]
Nycz, Jacek E. [2 ]
机构
[1] Gdansk Univ Technol, Dept Inorgan Chem, Fac Chem, PL-80952 Gdansk, Poland
[2] Univ Silesia, Dept Organ Chem, PL-40007 Katowice, Poland
关键词
D O I
10.1107/S1600536809001950
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The two symmetry independent molecules of the title compound, C(19)H(13)Cl(2)NO(4), show similar conformations with the acetyl group twisted strongly relative to the remaining, virtually flat (r. m. s. deviations = 0.0173 and 0.0065 angstrom), part of the molecule. The hydroxyl groups of the 8-hydroxyquinoline residues are involved in intramolecular O-H center dot center dot center dot N hydrogen bonds, which, in one case, forms a part of a three-center interaction. Intermolecular O-H center dot center dot center dot O hydrogen bonds assemble the molecules into a one-dimensional polymeric structure extended along the a axis. The 4-hydroxyphenyl group of one molecule forms an O-H center dot center dot center dot O hydrogen bond, in which the hydroxyl H atom is disordered, with its inversion center counterpart.
引用
收藏
页码:O515 / U1753
页数:14
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