Structural Features and Properties of Metal Complexes in Ionic Liquids: Application in Alkylation Reactions

被引：7

作者：

Chiappe, Cinzia ^{[1
]}

Ghilardi, Tiziana ^{[1
]}

Pomelli, Christian Silvio ^{[1
]}

机构：

[1] Univ Pisa, Dipartimento Farm, Via Bonanno 33, I-56126 Pisa, Italy

来源：

IONIC LIQUIDS (ILS) IN ORGANOMETALLIC CATALYSIS | 2015年 / 51卷

关键词：

Alkylation reactions; Ionic liquids; Metal speciation; Transition metals; INTRINSIC KINETICS; LEWIS ACIDITY; SPECIATION; ALUMINUM; ISOBUTANE; CATALYSIS; MIXTURES; CHLORIDE; ALCL3;

D O I：

10.1007/3418_2013_68

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-containing ionic liquids (ILs) represent a promising sub-class of "charged" liquids which increase the tunability of ILs combining the properties of common organic salts with magnetic, photophysical/optical or catalytic properties of the incorporated metal salts. In ILs lacking of coordinating groups on cation dissolution of metal salts is generally associated with the coordination of the metal cation with IL anion(s). Here we report on the anionic speciation of metals in ILs having either highly or poorly coordinating anions and we discuss some peculiar properties of these systems in the light of their structural features.

引用

页码：79 / 93

页数：15

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