Effect of surface-hydroxylated CdS nanoparticles on the morphological transformation of polystyrene-block-poly(ethylene oxide) thin films

被引：0
|
作者：
Yeh, SW [1 ]
Chang, YT [1 ]
Chou, CH [1 ]
Wei, KH [1 ]
机构：
[1] Natl Chiao Tung Univ, Dept Mat Sci & Engn, Hsinchu 30049, Taiwan
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 19期
关键词：
block copolymers; cadmium sulfide; hydrogen bond; nanoparticles; polystyrene-block-poly(ethylene oxide);
D O I：
暂无
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Polystyrene-block-poly(ethylene oxide) (SEO) block copolymer thin films, in which CdS clusters have been sequestered into the PEO domains of the SEO block copolymers, are found to induce the morphological transformation of PEO from cylinders to spheres, as shown by using atomic force microscopy (AFM), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). This transformation is caused by the presence of hydrogen-bonding interactions between surface-hydroxylated CdS and PEO, as confirmed by nuclear magnetic resonance (NMR) studies.
引用
收藏
页码：1680 / 1686
页数：7
相关论文
共 50 条
  • [41] Hydrogen-Bonding-Driven Complexation of Polystyrene-block-poly(ethylene oxide) Micelles with Poly(acrylic acid)
    Yang, Shuguang
    Yu, Xinfei
    Wang, Lian
    Tu, Yingfeng
    Zheng, Joseph X.
    Xu, Junting
    Van Horn, Ryan M.
    Cheng, Stephen Z. D.
    MACROMOLECULES, 2010, 43 (06) : 3018 - 3026
  • [42] Comicellization of polystyrene-block-poly(ethylene oxide) with cationic and anionic surfactants in aqueous solutions:: Indications and limits
    Bronstein, LM
    Chernyshov, DM
    Vorontsov, E
    Timofeeva, GI
    Dubrovina, LV
    Valetsky, PM
    Kazakov, S
    Khokhlov, AR
    JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (38): : 9077 - 9082
  • [43] Structure and Ionic Conductivity of Polystyrene-block-poly(ethylene oxide) Electrolytes in the High Salt Concentration Limit
    Chintapalli, Mahati
    Le, Thao N. P.
    Venkatesan, Naveen R.
    Mackay, Nikolaus G.
    Rojas, Adriana A.
    Thelen, Jacob L.
    Chen, X. Chelsea
    Devaux, Didier
    Balsara, Nitash P.
    MACROMOLECULES, 2016, 49 (05) : 1770 - 1780
  • [44] Conductive Properties of Inorganic and Organic TiO2/Polystyrene-block-Poly(ethylene oxide) Nanocomposites
    Gutierrez, Junkal
    Tercjak, Agnieszka
    Peponi, Laura
    Mondragon, Inaki
    JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (20): : 8601 - 8605
  • [45] Vesicle formation of polystyrene-block-poly (ethylene oxide) block copolymers induced by supercritical CO2 treatment
    Xu, Limei
    Zhang, Xiaokai
    Yang, Hui
    Li, Xue
    Li, Chunsheng
    Zhang, Shuxiang
    POLYMER, 2010, 51 (16) : 3808 - 3813
  • [46] Morphological Transitions of Symmetric Polystyrene-block-Poly(1,4-butadiene) Copolymers in Thin Films upon Solvent-Annealing
    Lee, Dong-Eun
    Kim, Eung-Gun
    Lee, Dong Hyun
    POLYMER-KOREA, 2012, 36 (04) : 542 - 548
  • [47] Poly(ethylene oxide)-block-polystyrene thin films morphology controlled by drying conditions and substrate topography
    Jenczyk, Jacek
    Coy, Emerson
    Jurga, Stefan
    EUROPEAN POLYMER JOURNAL, 2016, 75 : 234 - 242
  • [48] Morphological and optical behavior of thermoset matrix composites varying both polystyrene-block-poly(ethylene oxide) and TiO2 nanoparticle content
    Gutierrez, Junkal
    Mondragon, Inaki
    Tercjak, Agnieszka
    POLYMER, 2011, 52 (25) : 5699 - 5707
  • [49] Reversible polystyrene-block-poly(methyl methacrylate) copolymer films with perpendicular orientation by ultra-thin polystyrene substrates
    Wang, Juanjuan
    Shi, Weihe
    Luo, Zhengjie
    Chen, Shuangjun
    Xue, Kailai
    PROGRESS IN ORGANIC COATINGS, 2020, 147
  • [50] Reversible aggregation of polystyrene-block-poly(2-vinylpyridine)-block-poly(ethylene oxide) block copolymer micelles in acidic aqueous solutions
    Stepánek, M
    Matejícek, P
    Humpolícková, J
    Procházka, K
    LANGMUIR, 2005, 21 (23) : 10783 - 10790
12345