Pyrolysis kinetic analysis of the three pseudocomponents of biomass-cellulose, hemicellulose and lignin

被引：43
|
作者：
Chen, Tianju [1 ]
Li, Lingyue [1 ]
Zhao, Ruidong [1 ]
Wu, Jinhu [1 ]
机构：
[1] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc, Key Lab Biofuels, 189 Songling Rd, Qingdao 266101, Peoples R China
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2017年 / 128卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Pyrolysis; Biomass; Kinetic analysis; Pseudocomponent; Sinusoidally modulated temperature method; BIO-OIL; ACTIVATION-ENERGIES; MODULATED THERMOGRAVIMETRY; LIGNOCELLULOSIC BIOMASS; STRAW PYROLYSIS; REACTION MODEL; DECOMPOSITION; TEMPERATURE; BIOCHAR; REACTOR;
D O I：
10.1007/s10973-016-6040-3
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The pyrolysis kinetic analysis of the three pseudocomponents of biomass, namely cellulose, hemicellulose and lignin, were investigated using a thermogravimetric (TG) analyzer. The multi-peaks method was used to fit the Gaussian distribution model of DTG curves. The activation energies of three pseudocomponents pyrolysis were evaluated using sinusoidally modulated temperature method. The results showed that the multi-peaks methods can fit the DTG curves of cellulose, hemicellulose and lignin successfully. There was only one reaction stage for the pyrolysis of cellulose and hemicelluloses. There were two reaction stages for the pyrolysis of lignin. The average E was 112.6, 162.8 and 156.8 kJ mol(-1) for cellulose, hemicellulose and lignin, respectively.
引用
收藏
页码：1825 / 1832
页数：8
相关论文
共 50 条
  • [21] Volatile production from pyrolysis of cellulose, hemicellulose and lignin
    Zhao, Chenxi
    Jiang, Enchen
    Chen, Aihui
    JOURNAL OF THE ENERGY INSTITUTE, 2017, 90 (06) : 902 - 913
  • [22] Effects of Fe addition on pyrolysis characteristics of lignin, cellulose and hemicellulose
    Ge, Lichao
    Zhao, Can
    Zuo, Mingjin
    Du, Yuying
    Tang, Jie
    Chu, Huaqiang
    Wang, Yang
    Xu, Chang
    JOURNAL OF THE ENERGY INSTITUTE, 2023, 107
  • [23] NOx and N2O Precursors from Biomass Pyrolysis: Role of Cellulose, Hemicellulose and Lignin
    Ren, Qiangqiang
    Zhao, Changsui
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2013, 47 (15) : 8955 - 8961
  • [24] Cellulose-Hemicellulose and Cellulose-Lignin Interactions during Fast Pyrolysis
    Zhang, Jing
    Choi, Yong S.
    Yoo, Chang G.
    Kim, Tae H.
    Brown, Robert C.
    Shanks, Brent H.
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2015, 3 (02): : 293 - 301
  • [25] Modeling Study of Woody Biomass: Interactions of Cellulose, Hemicellulose, and Lignin
    Zhang, Xiaolei
    Yang, Weihong
    Blasiak, Wlodzimierz
    ENERGY & FUELS, 2011, 25 (10) : 4786 - 4795
  • [26] Experimental study on biomass reactive drying based on three major components: Cellulose, hemicellulose, and lignin
    Wang, Shicheng
    Guo, Xiaolei
    Zhang, Xu
    Lu, Haifeng
    Liu, Haifeng
    CHEMICAL ENGINEERING JOURNAL, 2025, 504
  • [27] A kinetic study of the acetylation of cellulose, hemicellulose and lignin components in wood
    Ramsden M.J.
    Blake F.S.R.
    Wood Science and Technology, 1997, 31 (1) : 45 - 50
  • [28] A kinetic study of the acetylation of cellulose, hemicellulose and lignin components in wood
    Ramsden, MJ
    Blake, FSR
    WOOD SCIENCE AND TECHNOLOGY, 1997, 31 (01) : 45 - 50
  • [29] Pyrolysis behavior and product distributions of biomass six group components: Starch, cellulose, hemicellulose, lignin, protein and oil
    Zong, Peijie
    Jiang, Yuan
    Tian, Yuanyu
    Li, Jie
    Yuan, Meng
    Ji, Yaoyao
    Chen, Minshen
    Li, Dawei
    Qiao, Yingyun
    ENERGY CONVERSION AND MANAGEMENT, 2020, 216
  • [30] The effect of temperature and hemicellulose-lignin, cellulose-lignin, and cellulose-hemicellulose on char yield from the slow pyrolysis of rice husk
    Gupta, Naveen Kumar
    Prakash, P.
    Kalaichelvi, P.
    Sheeba, K. N.
    ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2016, 38 (10) : 1428 - 1434
12345