Storage capacity of hydrogen in tetrahydrothiophene and furan clathrate hydrates

被引：50
|
作者：
Tsuda, Takaaki [1 ]
Ogata, Kyohei [1 ]
Hashimoto, Shunsuke [1 ]
Sugahara, Takeshi [1 ]
Moritoki, Masato [1 ]
Ohgaki, Kazunari [1 ]
机构：
[1] Osaka Univ, Div Chem Engn, Grad Sch Engn Sci, Osaka 5608531, Japan
来源：
CHEMICAL ENGINEERING SCIENCE | 2009年 / 64卷 / 19期
关键词：
Clathrate hydrate; Phase equilibria; Storage capacity; Stability; Absorption; Gases; THERMODYNAMIC STABILITY;
D O I：
10.1016/j.ces.2009.06.018
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The storage capacity of hydrogen in the tetrahydrothiophene and furan hydrates was investigated by means of pressure-volume-temperature measurement. The hydrogen-absorption rate of tetrahydrothiophene and furan hydrates is much larger than that of tetrahydrofuran hydrate in spite of same crystal structure (structure-II). The storage amount of hydrogen at 275.1 K is about 1.2 mol (hydrogen)/mol (tetrahydrothiophene or furan hydrate) (similar to 0.6mass%) at 41.5MPa, which is coincident with that of tetrahydrofuran hydrate. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4150 / 4154
页数：5
相关论文
共 50 条
  • [41] FORMATION OF CLATHRATE HYDRATES IN HYDROGEN-RICH GASES
    HOLDER, GD
    STEPHENSON, JL
    JOYCE, JJ
    JOHN, VT
    KAMATH, VA
    MALEKAR, S
    INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1983, 22 (01): : 170 - 171
  • [42] The influence of pressure on the stability of clathrate hydrates of hydrogen and tetrahydrofuran
    Mamatkulov, Sh. I.
    Ismailova, O. B.
    Ashirmatov, S.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (05) : 760 - 766
  • [43] COMP 252-Simulations of hydrogen clathrate hydrates
    Freeman, David L.
    Cardoen, Wim
    Curotto, Emanuele
    Doll, J. D.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 235
  • [44] Hydrogen storage in clathrate materials
    Prasad, Prasad R.
    Sum, Amadeu K.
    Sloan, E. Dendy
    Koh, Carolyn A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
  • [45] Inelastic neutron scattering from hydrogen clathrate hydrates
    Ulivi, L.
    Celli, M.
    Giannasi, A.
    Ramirez-Cuesta, A. J.
    Zoppi, M.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2008, 20 (10)
  • [46] Synthesis, structure, and property relations of hydrogen clathrate hydrates
    Grim, Gary
    Matsumoto, Yuki
    Sloan, Dendy
    Sum, Amadeu K.
    Koh, Carolyn A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [47] Theoretical description of phase diagrams of hydrogen clathrate hydrates
    Belosludov, Rodion
    Mizuseki, Hiroshi
    Kawazoe, Yoshiyuki
    Subbotin, Oleg
    Belosludov, Vladimir
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [48] Synthesis and Characterization of sI Clathrate Hydrates Containing Hydrogen
    Grim, R. Gary
    Kerkar, Prasad B.
    Shebowich, Michele
    Arias, Melissa
    Sloan, E. Dendy
    Koh, Carolyn A.
    Sum, Amadeu K.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (34): : 18557 - 18563
  • [49] Hydrogen storage in clathrate materials
    Prasad, Prasad R.
    Sugahara, T.
    Kim, Y.
    Sum, Amadeu K.
    Sloan, E. Dendy
    Koh, Carolyn A.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [50] Thermodynamic predictions of various tetrahydrofuran and hydrogen clathrate hydrates
    Strobel, Timothy A.
    Koh, Carolyn A.
    Sloan, E. Dendy
    FLUID PHASE EQUILIBRIA, 2009, 280 (1-2) : 61 - 67
12345