Storage capacity of hydrogen in tetrahydrothiophene and furan clathrate hydrates

被引：50
|
作者：
Tsuda, Takaaki [1 ]
Ogata, Kyohei [1 ]
Hashimoto, Shunsuke [1 ]
Sugahara, Takeshi [1 ]
Moritoki, Masato [1 ]
Ohgaki, Kazunari [1 ]
机构：
[1] Osaka Univ, Div Chem Engn, Grad Sch Engn Sci, Osaka 5608531, Japan
来源：
CHEMICAL ENGINEERING SCIENCE | 2009年 / 64卷 / 19期
关键词：
Clathrate hydrate; Phase equilibria; Storage capacity; Stability; Absorption; Gases; THERMODYNAMIC STABILITY;
D O I：
10.1016/j.ces.2009.06.018
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The storage capacity of hydrogen in the tetrahydrothiophene and furan hydrates was investigated by means of pressure-volume-temperature measurement. The hydrogen-absorption rate of tetrahydrothiophene and furan hydrates is much larger than that of tetrahydrofuran hydrate in spite of same crystal structure (structure-II). The storage amount of hydrogen at 275.1 K is about 1.2 mol (hydrogen)/mol (tetrahydrothiophene or furan hydrate) (similar to 0.6mass%) at 41.5MPa, which is coincident with that of tetrahydrofuran hydrate. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4150 / 4154
页数：5
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