Graphene/Polyaniline nanocomposite as electrode material for membrane capacitive deionization

被引:77
|
作者
Yan, Caijuan [1 ]
Kanaththage, Yasodinee Wimalasiri [1 ]
Short, Rob [2 ]
Gibson, Christopher T. [3 ]
Zou, Linda [1 ]
机构
[1] Univ S Australia, SA Water Ctr Water Management & Reuse, Adelaide, SA 5095, Australia
[2] Univ S Australia, Mawson Inst, Adelaide, SA 5095, Australia
[3] Flinders Univ S Australia, Sch Chem & Phys Sci, Flinders Ctr Nanoscale Sci & Technol, Adelaide, SA 5001, Australia
基金
澳大利亚研究理事会;
关键词
Membrane CDI; Graphene; Polyaniline; Electrosorption; Nanocomposite; COMPOSITE FILM ELECTRODES; CARBON AEROGEL ELECTRODES; RAMAN-SPECTROSCOPY; POLYANILINE; GRAPHENE; NANOTUBES; ELECTROSORPTION; DESALINATION; POLYMER; WATER;
D O I
10.1016/j.desal.2014.03.041
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Capacitive deionization (CDI) is a novel ion removal technology that uses static electrical force to drive ions to the charged electrode and stores the ions into porous structure of the electrode. Graphene and graphene nanocomposites are considered promising materials for electrodes because of its good conductivity and extraordinarily high specific surface area. Graphene/Polyaniline nanocomposite was chosen that aims to increase the ion-electrosorption capacitance of graphene. In this work, graphene nanosheets were obtained by reducing oxidized graphite flasks. Graphene/Polyaniline (G/PANI) nanocomposites were synthesized by chemical polymerization of aniline in the presence of dispersed graphene sheets. The morphology and electrochemical property of the composite were characterized. The ion removal performance of the composite was determined by using a membrane capacitive deionization (CDI) bench-scale system. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:274 / 279
页数:6
相关论文
共 50 条
  • [31] Theory of membrane capacitive deionization including the effect of the electrode pore space
    Biesheuvel, P. M.
    Zhao, R.
    Porada, S.
    van der Wal, A.
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 360 (01) : 239 - 248
  • [32] Membrane-spacer assembly for flow-electrode capacitive deionization
    Lee, Ki Sook
    Cho, Younghyun
    Choo, Ko Yeon
    Yang, SeungCheol
    Han, Moon Hee
    Kim, Dong Kook
    APPLIED SURFACE SCIENCE, 2018, 433 : 437 - 442
  • [33] Efficient and stable operation of capacitive deionization assessed by electrode and membrane asymmetry
    Barcelos, Kamilla M.
    Oliveira, Kaique S. G. C.
    Silva, Domingos S. A.
    Urquieta-Gonzalez, Ernesto A.
    Ruotolo, Luis A. M.
    ELECTROCHIMICA ACTA, 2021, 388
  • [34] Determination of the electrode potential causing Faradaic reactions in membrane capacitive deionization
    Choi, Jae-Hwan
    DESALINATION, 2014, 347 : 224 - 229
  • [35] Preparation and application of reduced graphene oxide as the conductive material for capacitive deionization
    Nugrahenny, Ayu Tyas Utami
    Kim, Jiyoung
    Kim, Sang-Kyung
    Peck, Dong-Hyun
    Yoon, Seong-Ho
    Jung, Doo-Hwan
    CARBON LETTERS, 2014, 15 (01) : 38 - 44
  • [36] Removal of ammonium ions by capacitive deionization and membrane capacitive deionization units
    Sakar, Hacer
    Karatas, Okan
    Canbolat, Cigdem Balcik
    Keskinler, Bulent
    Karagunduz, Ahmet
    DESALINATION AND WATER TREATMENT, 2017, 75 : 260 - 267
  • [37] Potential limits of capacitive deionization and membrane capacitive deionization for water electrolysis
    Kim, Y. -H.
    Tang, K.
    Chang, J.
    Sharma, K.
    Yiacoumi, S.
    Mayes, R. T.
    Bilheux, H. Z.
    Santodonato, L. J.
    Tsouris, C.
    SEPARATION SCIENCE AND TECHNOLOGY, 2019, 54 (13) : 2112 - 2125
  • [38] Towards Electrochemical Water Desalination Techniques: A Review on Capacitive Deionization, Membrane Capacitive Deionization and Flow Capacitive Deionization
    Folaranmi, Gbenro
    Bechelany, Mikhael
    Sistat, Philippe
    Cretin, Marc
    Zaviska, Francois
    MEMBRANES, 2020, 10 (05)
  • [39] Preparation of Sulfonated Graphene/Activated Carbon Composite Electrode for Asymmetric Capacitive Deionization
    Lu Miao
    Liu Jianyun
    Wang Shiping
    Cheng Jian
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2014, 35 (07): : 1546 - 1552
  • [40] Electrode materials for capacitive deionization: A review
    Zhao, Xiaoyu
    Wei, Hongxin
    Zhao, Huachao
    Wang, Yanfei
    Tang, Na
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2020, 873 (873)