Metal-Free Enantioselective Hydroxyamination of Aldehydes with Nitrosocarbonyl Compounds Catalyzed by an Axially Chiral Amine

被引：61
|
作者：
Kano, Taichi [1 ]
Shirozu, Fumitaka [1 ]
Maruoka, Keiji [1 ]
机构：
[1] Kyoto Univ, Dept Chem, Grad Sch Sci, Sakyo Ku, Kyoto 6068502, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 48期
基金：
日本学术振兴会;
关键词：
ASYMMETRIC ALPHA-AMINOXYLATION; NITROSO ALDOL REACTION; DIELS-ALDER REACTION; AEROBIC OXIDATION; HYDROXAMIC ACIDS; OXYAMINATION; EFFICIENT; CHEMISTRY; ENAMINE; FACILE;
D O I：
10.1021/ja4099627
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first example of a highly regio- and enantioselective hydroxyamination of aldehydes with in situ generated nitrosocarbonyl compounds from hydroxamic acid derivatives was realized by combined use of TEMPO and BPO as the oxidant in the presence of a binaphthyl-modified amine catalyst.
引用
收藏
页码：18036 / 18039
页数：4
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