Cation-anion interactions via hydrogen bonding; synthesis, characterization and single crystal X-ray structure of [Cu(phen)3](1,3-benzenedisulphonate)•7H2O

被引：10

作者：

Sharma, R. P. ^{[1
]}

Kumar, S. ^{[1
]}

Saini, A. ^{[1
]}

Venugopalan, P. ^{[1
]}

Rodriguez-Dieguez, A. ^{[2
]}

Salas, J. M. ^{[2
]}

机构：

[1] Panjab Univ, Dept Chem, Chandigarh 160014, India

[2] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1071卷

关键词：

Phenanthroline; Non-covalent interactions; Spectroscopic techniques; Single crystal X-ray; COPPER(II) COMPLEXES; MOLECULAR-STRUCTURE; DNA-BINDING; METAL-IONS; RECEPTORS; LIGANDS;

D O I：

10.1016/j.molstruc.2014.04.046

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new copper(II) complex, [Cu(phen)(3)](1,3-benzenedisulphonate)center dot 7H(2)O, has been synthesized by reacting hydrated cupric chloride with phenanthroline (phen) and disodium salt of 1,3-benzenedisulphonate in ethanol-water mixture. It has been characterized on the basis of elemental analysis, spectroscopic techniques (FT-IR, UV-visible, EPR), thermogravimetric analyses and single crystal X-ray structure determination. A detailed packing analysis has revealed the existence of non-covalent interactions which stabilize the crystal lattice. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：11 / 17

页数：7

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