Cation-anion interactions via hydrogen bonding; synthesis, characterization and single crystal X-ray structure of [Cu(phen)3](1,3-benzenedisulphonate)•7H2O

被引：10
|
作者：
Sharma, R. P. [1 ]
Kumar, S. [1 ]
Saini, A. [1 ]
Venugopalan, P. [1 ]
Rodriguez-Dieguez, A. [2 ]
Salas, J. M. [2 ]
机构：
[1] Panjab Univ, Dept Chem, Chandigarh 160014, India
[2] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1071卷
关键词：
Phenanthroline; Non-covalent interactions; Spectroscopic techniques; Single crystal X-ray; COPPER(II) COMPLEXES; MOLECULAR-STRUCTURE; DNA-BINDING; METAL-IONS; RECEPTORS; LIGANDS;
D O I：
10.1016/j.molstruc.2014.04.046
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new copper(II) complex, [Cu(phen)(3)](1,3-benzenedisulphonate)center dot 7H(2)O, has been synthesized by reacting hydrated cupric chloride with phenanthroline (phen) and disodium salt of 1,3-benzenedisulphonate in ethanol-water mixture. It has been characterized on the basis of elemental analysis, spectroscopic techniques (FT-IR, UV-visible, EPR), thermogravimetric analyses and single crystal X-ray structure determination. A detailed packing analysis has revealed the existence of non-covalent interactions which stabilize the crystal lattice. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：11 / 17
页数：7
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