Sequential H-migration reactions in the formation of [Os-3(mu(2)-H)(mu(2)-PHMe)(CO)(10)] and [Os-3(mu(2)-H)(2)(mu(3)-PMe)(CO)(9)] during the reaction between the phosphinidene complex [W(PMe)(CO)(5)] and [Os-3(mu(2)-H)(2)(CO)(10)]

被引：0

作者：

Ajulu, FA

Mathey, F

Nixon, JF

机构：

[1] UNIV SUSSEX,SCH CHEM & MOL SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

[2] ECOLE POLYTECH,DCPH,F-91128 PALAISEAU,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 543卷 / 1-2期

关键词：

D O I：

10.1016/S0022-328X(97)00097-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The transient phosphinidene complex [W(PMe)(CO)(5)] reacts with the unsaturated [Os-3(mu(2)-H)(2)(CO)(10)] cluster to afford [Os-3(mu(2)- H)(mu(2)-PHMe)(CO)(10)] and subsequently [Os-3(mu(2)-H)(2)(mu(3)-PMe)(CO)(9)] via H-migration reactions involving both transfer from Os to P and from P to Os. (C) 1997 Elsevier Science S.A.

引用

页码：245 / 247

页数：3

共 50 条

[21] Protonation of triosmium clusters Os-3(CO)(9)(mu-CO)(mu(3)-2 sigma,eta(2)-HC CR) and Os-3(mu-H)(CO)(9)(mu(3)-sigma,2 eta(2)-C CR) (R=CH2OH, CMe(2)OH, C(Me)=CH2)
Krivykh, VV
Kizas, OA
Vorontsov, EV
Dolgushin, FM
Yanovsky, AI
Struchkov, YT
Koridze, AA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 508 (1-2) : 39 - 47
[22] Synthesis of triosmium alkylidyne clusters incorporating bis(diphenylphosphino)alkane type ligands. Crystal structures of [{Os-3(mu-H)(2)(CO)(9)(mu(3)-C)}(2)(mu-dppp)] (dppp equals bis( diphenylphosphino)propane) and [Os-3(mu-H)(2)(CO)(8)(mu(3)-CPPh(2)CH(2)PPh(2))]
Choi, YY
Wong, WY
Wong, WT
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 518 (1-2) : 227 - 233
[23] Synthesis and protonation of an Os-3(mu-H)(CO)(10)(mu-sigma,eta(2)-C CCMe2OMe) cluster
Krivykh, VV
Kizas, OA
Vorontsov, EV
Koridze, AA
RUSSIAN CHEMICAL BULLETIN, 1996, 45 (12) : 2840 - 2842
[24] Systematic CO dissociation kinetics of (mu(2)-H)(H)Os-3(CO)(10)L clusters (L=P-donor ligands)
Hudson, RHE
Poe, AJ
INORGANICA CHIMICA ACTA, 1997, 259 (1-2) : 257 - 263
[25] Reactivity of [M(3)(mu-H)(CO)(10)(mu-PH2)] (M=Ru,Os) towards organic and organometallic electrophiles; Evidence for electrophilic endo-attack at the phosphido moiety of [Os-3(mu-H)(CO)(10)(mu-PH2)]
Heuer, L
Nordlander, E
Johnson, BFG
Lewis, J
Raithby, PR
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1995, 103 (1-4): : 241 - 252
[26] REACTIONS OF TRIOSMIUM CLUSTERS OS-3(CO)(11)(MECN) AND (MU-H)OS-3(CO)(10)(MU-OH) WITH L-ALPHA-SERINE ETHYL-ESTER AND ETHANOLAMINE
MAKSAKOV, VA
KIRIN, VP
TKACHEV, SV
RUSSIAN CHEMICAL BULLETIN, 1994, 43 (03) : 485 - 490
[27] SYNTHESIS OF THIOLATO HETEROMETALLIC CLUSTERS FROM THE REACTION OF OS-3(CO)(9)(MCME)(MU-H)(MU-SME) WITH GPW(CO)(3)H
TSAY, CW
TU, WC
CHI, Y
PENG, SM
LEE, GH
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1994, 41 (06) : 621 - 625
[28] SYNTHESIS OF NOVEL MIXED-METAL CLUSTERS OF MERCURY AND OSMIUM - CRYSTAL AND MOLECULAR-STRUCTURES OF CIS-[OS(CO)(4)((MU-HG)OS-3(CO)(10)(MU-ETA(2)-CH=CHPH))(2)] AND [(OS-3(CO)(10)(MU-ETA(2)-CH=CHPH))(2)(MU(4)-HG)]
AU, YK
WONG, WT
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (08): : 1389 - 1390
[29] GROUP-IV DERIVATIVES OF OS3(MU-H)2(CO)10 - STRUCTURES OF HOS3(MU-H)2(CO)10(SIHPH2) AND OS3(MU-H)2(CO)10(SNME3)2
EINSTEIN, FWB
POMEROY, RK
WILLIS, AC
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 311 (03) : 257 - 268
[30] DECACARBONYLDI-MU-HYDRIDOTRIOSMIUM - OS3(MU-H)2(CO)10
KAESZ, HD
INORGANIC SYNTHESES, 1990, 28 : 238 - 240

← 1 2 3 4 5 →