Sequential H-migration reactions in the formation of [Os-3(mu(2)-H)(mu(2)-PHMe)(CO)(10)] and [Os-3(mu(2)-H)(2)(mu(3)-PMe)(CO)(9)] during the reaction between the phosphinidene complex [W(PMe)(CO)(5)] and [Os-3(mu(2)-H)(2)(CO)(10)]

被引：0

作者：

Ajulu, FA

Mathey, F

Nixon, JF

机构：

[1] UNIV SUSSEX,SCH CHEM & MOL SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

[2] ECOLE POLYTECH,DCPH,F-91128 PALAISEAU,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 543卷 / 1-2期

关键词：

D O I：

10.1016/S0022-328X(97)00097-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The transient phosphinidene complex [W(PMe)(CO)(5)] reacts with the unsaturated [Os-3(mu(2)-H)(2)(CO)(10)] cluster to afford [Os-3(mu(2)- H)(mu(2)-PHMe)(CO)(10)] and subsequently [Os-3(mu(2)-H)(2)(mu(3)-PMe)(CO)(9)] via H-migration reactions involving both transfer from Os to P and from P to Os. (C) 1997 Elsevier Science S.A.

引用

页码：245 / 247

页数：3

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