Hydrogenation of β-N-Substituted and β-N,N-Disubstituted Enamino Esters in the Presence of Iridium(I) Catalyst

被引：7

作者：

Hebbache, Hania ^{[1
,2
]}

Hank, Zakia ^{[2
]}

Bruneau, Christian ^{[1
]}

Renaud, Jean-Luc ^{[3
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France

[2] Univ Sci & Technol Houari Boumed, Lab Electrochim Corros Met & Chim Minerale, Fac Chim, Bab Ezzouar, Alger, Algeria

[3] Univ Caen, ENSICAEN, Lab Chim Mol & Thioorgan, UMR 6507,INC3M,FR 3038, F-14050 Caen, France

来源：

SYNTHESIS-STUTTGART | 2009年 / 15期

关键词：

catalysis; hydrogenation; iridium; beta-amino esters; AMINO-ACID-DERIVATIVES; ASYMMETRIC HYDROGENATION; ENANTIOSELECTIVE SYNTHESIS; CONJUGATE ADDITION; EFFICIENT SYNTHESIS; LACTAMS; AMIDES; AMINOHYDROXYLATION; CYCLOADDITION; CISPENTACIN;

D O I：

10.1055/s-0029-1217405

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several new beta-amino esters were prepared in two simple steps from beta-keto ester derivatives and primary and secondary amines under mild conditions. The hydrogenation of various enamino esters was performed at 50 degrees C in the presence of iridium catalysts. The new beta-N-substituted amino esters were isolated in high yields.

引用

页码：2627 / 2633

页数：7

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