Layer-by-layer construction of nanostructured porphyrin-fullerene electrodes

被引:62
|
作者
Guldi, DM [1 ]
Pellarini, F
Prato, M
Granito, C
Troisi, L
机构
[1] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA
[2] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy
[3] Univ Lecce, Dipartimento Sci & Tecnol Biol & Ambientali, I-73100 Lecce, Italy
关键词
D O I
10.1021/nl025703o
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The fabrication of high quality, robust, and photoactive ITO electrodes is reported. Electrostatic and van der Waals interactions have been used for the step-by-step deposition of layers containing a fullerene-porphyrin dyad as the active layer. The new electrodes give rise to improved light harvesting features in the visible, with absorbances as high as 0.2 (i.e., at the Soret band of H2P) for a monolayer coverage and IPCEs of 0.38% and 0.6% under anaerobic and aerobic conditions, respectively.
引用
收藏
页码:965 / 968
页数:4
相关论文
共 50 条
  • [21] Hole Mobility in Porphyrin- and Porphyrin-Fullerene Electropolymers
    Brennan, Bradley J.
    Liddell, Paul A.
    Moore, Thomas A.
    Moore, Ana L.
    Gust, Devens
    JOURNAL OF PHYSICAL CHEMISTRY B, 2013, 117 (01): : 426 - 432
  • [22] Synthesis of closely spaced porphyrin-fullerene
    Imahori, H
    Sakata, Y
    CHEMISTRY LETTERS, 1996, (03) : 199 - 200
  • [23] Layer-by-layer growth of electrostatically assembled multilayer porphyrin films
    Araki, K
    Wagner, MJ
    Wrighton, MS
    LANGMUIR, 1996, 12 (22) : 5393 - 5398
  • [24] Conjugated porphyrin-fullerene systems.
    Vail, SA
    Schuster, DI
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U164 - U164
  • [25] Nanostructured Layer-by-Layer Polyelectrolyte Containers to Switch Biofilm Fluorescence
    Nikitina, Anna A.
    Ulasevich, Sviatlana A.
    Kassirov, Ilia S.
    Bryushkova, Ekaterina A.
    Koshel, Elena I.
    Skorb, Ekaterina V.
    BIOCONJUGATE CHEMISTRY, 2018, 29 (11) : 3793 - 3799
  • [26] Optical fiber sensors based on Layer-by-Layer nanostructured films
    Arregui, Francisco J.
    Matias, Ignacio R.
    Corres, Jesus M.
    Del Villar, Ignacio
    Goicoechea, Javier
    Ruiz Zamarreno, Carlos
    Hernaez, Miguel
    Claus, Richard O.
    EUROSENSORS XXIV CONFERENCE, 2010, 5 : 1087 - 1090
  • [27] Immobilization of liposomes in nanostructured layer-by-layer films containing dendrimers
    Moraes, Marli L.
    Baptista, Mauricio S.
    Itri, Rosangela
    Zucolotto, Valtencir
    Oliveira, Osvaldo N., Jr.
    MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2008, 28 (04): : 467 - 471
  • [28] Template synthesis of nanostructured materials via layer-by-layer assembly
    Wang, Yajun
    Angelatos, Alexandra S.
    Caruso, Frank
    CHEMISTRY OF MATERIALS, 2008, 20 (03) : 848 - 858
  • [29] Layer-by-layer nanostructured hybrid films of polyaniline and vanadium oxide
    Ferreira, M
    Zucolotto, V
    Huguenin, F
    Torresi, RM
    Oliveira, ON
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2002, 2 (01) : 29 - 32
  • [30] Multilayered construction of glucose oxidase and silica nanoparticles on Au electrodes based on layer-by-layer covalent attachment
    Sun, YY
    Yan, F
    Yang, WS
    Sun, CQ
    BIOMATERIALS, 2006, 27 (21) : 4042 - 4049