Synthesis, characterization and molecular structures of Ni(II) complexes derived from Schiff base pyridylimine ligands

被引：10

作者：

Roberto Pioquinto-Mendoza, J. ^{[1
]}

Alberto Rosas-Ortiz, Jaime ^{[1
]}

Reyes-Martinez, Reyna ^{[1
]}

Conelly-Espinosa, Patricia ^{[1
]}

Toscano, Ruben A. ^{[1
]}

German-Acacio, Juan M. ^{[2
]}

Avila-Sorrosa, Alcives ^{[3
]}

Baldovino-Pantaleon, Oscar ^{[4
]}

Morales-Morales, David ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

[2] Univ Nacl Autonoma Mexico, Inst Nacl Ciencias Med & Nutr SZ, Res Support Network, CIC UNAM, Mexico City 04510, DF, Mexico

[3] Inst Politecn Nacl, Escuela Nacl Ciencias Biol, Dept Quim Organ, Mexico City 11340, DF, Mexico

[4] Univ Autonoma Tamaulipas, UAM Reynosa Rodhe, Reynosa 88779, Tamaulipas, Mexico

来源：

INORGANICA CHIMICA ACTA | 2015年 / 438卷

关键词：

Nickel complexes; Pyridylimine ligands; Crystal structures; Supramolecular arrangements; Non-covalent interactions; Schiff base compounds; HYDROGEN-BOND PATTERNS; GRAPH-SET ANALYSIS; PALLADIUM(II) COMPLEXES; CRYSTAL-STRUCTURES; CU(II) COMPLEXES; PD-II; NI-II; NICKEL(II); IMINE; CONDUCTIVITY;

D O I：

10.1016/j.ica.2015.09.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structural characterization of Ni(II) complexes derived from N1,N4-bis(pyridin-2-yl-methylene) butane-1,4-diamine (L1) and N1,N4-bis(1-(pyridin-2-yl)ethylidene)butane-1,4-diamine (L2) is described. The paramagnetic Ni(II) complexes NiL1 and NiL2 were fully characterized and their structures unequivocally determined by single crystal X-ray diffraction techniques. The molecular structures of NiL1 and NiL2 exhibited the ligands L1 and L2 coordinated in a kappa(4)-N,N,N,N-tetradentate fashion. The subtle changes in the ligands defines the ionic o neutral nature of the complexes. Furthermore, in the solid state both complexes exhibit extended hydrogen-bond networks. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：146 / 152

页数：7

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