Vibrationally autoionizing electron wave packets in a combined Coulombic and electric field

被引:3
|
作者
Stavros, VG [1 ]
Fielding, HH [1 ]
机构
[1] Kings Coll London, Dept Chem, London WC2R 2LS, England
来源
PHYSICAL REVIEW A | 1999年 / 60卷 / 06期
关键词
D O I
10.1103/PhysRevA.60.4774
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The optical Ramsey method is employed to investigate molecular electron wave-pocket dynamics in the angular coordinate. Time-resolved spectra are presented for vibrationally autoionizing Rydberg electron wave packets with principal quantum numbers n=17-21, excited between the v(+)=0 and v(+)=1 ionization limits, in the presence of electric fields in the range 0.7-1.4 kV cm(-1). A regular, almost dispersion-free beating in the angular coordinate is observed for wave packets created using light which is polarized perpendicular to the direction of the external de electric field. [S1050-2947(99)07512-5].
引用
收藏
页码:4774 / 4780
页数:7
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