Experimental Study on the Thermal Effect during Gas Adsorption and Desorption on the Coal Surface

被引:17
|
作者
Hao, Jianfeng [2 ]
Liang, Bing [1 ]
Sun, Weiji [1 ]
机构
[1] Liaoning Tech Univ, Sch Mech & Engn, Fuxin 123000, Liaoning, Peoples R China
[2] Liaoning Tech Univ, Coll Min, Fuxin 123000, Liaoning, Peoples R China
来源
ACS OMEGA | 2021年 / 6卷 / 02期
基金
中国国家自然科学基金;
关键词
WIDE TEMPERATURE-RANGE; ACTIVATED CARBON; ISOSTERIC HEAT; METHANE; SORPTION; THERMODYNAMICS; CO2; DEPENDENCE; CAPACITY; KINETICS;
D O I
10.1021/acsomega.0c05505
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The thermal effect of coal adsorption/desorption gas is very important for understanding the evolution of coal temperature and interaction between coal and gas during coal and gas outburst. The pressure difference between the high gas pressure area in front of the working face and the low gas pressure area near the coal wall may affect the adsorption/desorption thermal effect. In order to reveal the characteristics of the coal adsorption/desorption gas thermal effect at different pressure differences, a thermo-hydro-mechanical-coupled experimental system of coal and gas was designed. Taking no.3 coal from Xinjing Mine as the research object, the characteristics of the coal adsorption/desorption gas thermal effect under different pressure differences are studied by using the cycle-step experiment method. It is found that coal adsorbs gas to release heat, while coal desorbs gas to absorb heat. Also, the temperature variation and temperature accumulation caused by adsorption are greater than those caused by desorption. Under the same pressure difference, the temperature increase rate during the adsorption changes from large to small, and the temperature variation gradually decreases; the temperature decrease rate during the desorption changes from small to large, and the temperature variation gradually increases; desorption is the reverse process of adsorption. The relation between temperature variation and gas pressure is linear, and the increasing range of temperature variation gradually decreases with the increase of pressure difference. The relation between temperature accumulation and gas pressure conforms to an exponential function, and the decreasing range of temperature accumulation gradually decreases with the increase of pressure difference. The greater the pressure difference, the greater is the energy variation caused by the adsorption/desorption thermal effect. The experimental results of different pressure differences can reflect the characteristics of the coal adsorption/desorption gas thermal effect under different geological structures or outburst types.
引用
收藏
页码:1603 / 1611
页数:9
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