Preparation of hydroxyapatite hydrogel for bone-like materials via novel self-initiated photocatalytic polymerization

被引:7
|
作者
Han, Apichart [1 ]
Rujijanagul, Gobwute [3 ]
Randorn, Chamnan [1 ,2 ]
机构
[1] Chiang Mai Univ, Dept Chem, Fac Sci, Chiang Mai 50200, Thailand
[2] Chiang Mai Univ, Fac Sci, Mat Sci Res Ctr, Chiang Mai 50200, Thailand
[3] Chiang Mai Univ, Fac Sci, Dept Phys & Mat Sci, Chiang Mai 50200, Thailand
关键词
Hydrogel; Hydroxyapatite; Bone-like material; Self-initiation; Photocatalysis; SBF; COMPOSITES; NANOPARTICLES;
D O I
10.1016/j.matlet.2017.01.098
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Here, a novel polyacrylamide (PAM)/hydroxyapatite (HA) composite hydrogel was prepared by the self initiation of hydroxyapatite via its photocatalytic activity. The radical used as the initiator was produced during irradiation and can initiate the formation of the well-distributed HA in the PAM/HA composite. The in vitro bioactivity in SBF of the novel self-initiated PAM/HA(Ti) hydrogel was faster and better than the conventionally synthesized polyacrylamide hydrogel. The faster formation and larger amount of new apatite in SBF can be observed in the SEM images. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:142 / 145
页数:4
相关论文
共 50 条
  • [41] Preparation Magnetite Core/Coated with Polystyrene Shell Hybrid Materials via Redox Interfacial-Initiated Emulsion Polymerization
    Liu, Weijun
    Zhang, Zhicheng
    POLYMER COMPOSITES, 2010, 31 (11) : 1846 - 1852
  • [42] Cross-cultural self-preparation of Australian self-initiated expatriates for working and living in South Korea: 'Stumped like a bonsai: A show of what could have been'
    Despotovic, William Vuk
    Hutchings, Kate
    McPhail, Ruth
    ASIA PACIFIC JOURNAL OF HUMAN RESOURCES, 2015, 53 (02) : 241 - 259
  • [43] Preparation and characterization of coaxial mullite/polypyrrole fibrous nanocomposites via self-assembling and in situ surface-initiated polymerization
    Yang, Chao
    Mo, Haodao
    Zang, Limin
    Qiu, Jianhui
    Wang, Xue
    You, Hui
    POLYMER COMPOSITES, 2014, 35 (05) : 892 - 899
  • [44] Synthesis of novel sunflower-like silica/polypyrrole nanocomposites via self-assembly polymerization
    Yang, XM
    Dai, TY
    Lu, Y
    POLYMER, 2006, 47 (01) : 441 - 447
  • [47] Novel one-step synthesis and characterization of bone-like carbonated apatite from calcium carbonate, calcium hydroxide and orthophosphoric acid as economical starting materials
    Doan Pharn Minh
    Ngoc Dung Tran
    Nzihou, Ange
    Sharrock, Patrick
    MATERIALS RESEARCH BULLETIN, 2014, 51 : 236 - 243
  • [48] Novel one-step synthesis and characterization of bone-like carbonated apatite from calcium carbonate, calcium hydroxide and orthophosphoric acid as economical starting materials
    Pham Minh, Doan
    Tran, Ngoc Dung
    Nzihou, Ange
    Sharrock, Patrick
    Pham Minh, D. (doan.phamminh@mines-albi.fr), 1600, Elsevier Ltd (51): : 236 - 243
  • [49] High-efficiency preparation of poly(2-methacryloyloxyethyl phosphorylcholine) grafting layer on poly(ether ether ketone) by photoinduced and self-initiated graft polymerization in an aqueous solution in the presence of inorganic salt additives
    Shiojima, Taro
    Inoue, Yuuki
    Kyomoto, Masayuki
    Ishihara, Kazuhiko
    ACTA BIOMATERIALIA, 2016, 40 : 38 - 45
  • [50] Preparation and characterization of novel MicroPCMs (microencapsulated phase-change materials) with hybrid shells via the polymerization of two alkoxy silanes
    Li, Wenhong
    Song, Guolin
    Li, Shuhua
    Yao, Youwei
    Tang, Guoyi
    ENERGY, 2014, 70 : 298 - 306