5,5′-Di-4-pyridyl-2,2′-(5-tert-butyl-m-phenylene)bis(1,3,4-oxadiazole)

被引:1
|
作者
Ono, Katsuhiko [1 ]
Tsukamoto, Kenichi [1 ]
Tomura, Masaaki [2 ]
机构
[1] Nagoya Inst Technol, Dept Mat Sci & Engn, Showa Ku, Nagoya, Aichi 4668555, Japan
[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
ORGANIC ELECTROLUMINESCENT; DEVICES;
D O I
10.1107/S1600536809027056
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C(24)H(20)N(6)O(2), is a novel 1,3,4-oxadiazole derivative which has potential as an electron-transporting material in organic electroluminescent (EL) devices. In the crystal, the molecular framework is almost planar with an r.m.s. deviation of 0.091 (4) angstrom and it exists in an E form. Intramolecular C-H center dot center dot center dot O and C-H center dot center dot center dot N hydrogen bonds are observed between the benzene and 1,3,4-oxadiazole rings. The tert-butyl group is disordered over two sites, with occupancy factors of 0.78 (1) and 0.22 (1) for the major and minor orientations, respectively. In the crystal structure, molecules aggregate via C-H center dot center dot center dot N interactions, forming molecular tapes along the b axis, which aggregate to form a molecular sheet via C-H center dot center dot center dot N interactions.
引用
收藏
页码:O1873 / U3103
页数:13
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