Laser spectroscopy of SrH. Time-resolved measurements of the A(2)Pi state

被引:8
|
作者
Berg, LE
Ekvall, K
Hishikawa, A
Kelly, S
McGuinness, C
机构
[1] UNIV TOKYO,DEPT PURE & APPL SCI,MEGURO KU,TOKYO 153,JAPAN
[2] UNIV DUBLIN TRINITY COLL,DEPT PHYS,DUBLIN 2,IRELAND
关键词
D O I
10.1016/0009-2614(96)00376-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the near-infrared and red wavelength region around 680-760 nm, the spectrum of the A(2) Pi-X(2) Sigma transition of gaseous SrH appears. By applying laser spectroscopic methods, a time-resolved experiment has been performed on the low-lying A(2) Pi state of strontium hydride. No local influences on the A(2) Pi state were found due to interactions with the low-lying A'(2) Delta state, as in the case of the BaH molecule. The following zero-pressure lifetime was obtained for the SrH molecule: tau(A(2) Pi(1/2) (upsilon'=0))=33.8+/-1.9 ns.
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页码:419 / 424
页数:6
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