Multianvil high-pressure high-temperature synthesis in solid state chemistry

被引:326
|
作者
Huppertz, H [1 ]
机构
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 2004年 / 219卷 / 06期
关键词
high pressure; high temperature; multianvil synthesis; borates;
D O I
10.1524/zkri.219.6.330.34633
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
During the last 60 years, new high pressure techniques and their exploitation have permitted the extension of attainable pressure/volume conditions, increased versatility of the apparatus, and hydrostaticity of the attained pressure in a remarkable way. In preparative solid state chemistry, high-pressure/high-temperature synthesis always played a minor role due to technical difficulties and costs. Piston-cylinder and Belt-apparatus both were limited to the working range up to 3 and 10 GPa, respectively. New technical developments, which allow synthesis up to 25 GPa, open up an enormous field of sample synthesis in solid state chemistry. In the following, a short overview on the most important developments in multianvil-techniques is given with respect to their applications for solid state chemistry under high-pressure conditions.
引用
收藏
页码:330 / 338
页数:9
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